There are below basically 2 suggestions to reach Porto comfortably from Lisbon:
1) Straight Transfer from Lisbon to Porto: Concierge Portugal Transfer Service
2) Transfer from Lisbon to Porto with Sightseeing Stops: Lisbon Private Tours Transfer Service
Porto is the second most important city in Portugal, after Lisbon, and a place with rich history.
Since Porto is 3h distance from Lisbon, and located in the north of Portugal, there are some interesting places where you can stop on the way (Obidos, Nazare, Aveiro, Coimbra, etc)
The best option is to combine Obidos and Nazare on the way to Porto, as they are located on the same highway and close to each other.
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